SKY-WAVE PROPAGATION AND THE SUN
The Earth’s atmosphere is composed primarily of nitrogen (78%), oxygen (21%) and argon (1%), with smaller amounts of a dozen other gases. Water vapor can account for as much as 5% of the atmosphere under certain conditions. This ratio of gases is maintained until an altitude of about 80 km (50 mi), when the mix begins to change. At the highest levels, helium and hydrogen predominate.
Solar radiation acts directly or indirectly on all levels of the atmosphere. Adjacent to the surface of the Earth, solar warming controls all aspects of the weather, powering wind, rain and other familiar phenomena. Solar ultraviolet (UV) radiation creates small concentrations of ozone (O3) molecules between 10 and 50 km (6 and 30 mi). Most UV radiation is absorbed by this process and never reaches the Earth.
At even higher altitudes, UV and X-ray radiation partially ionize atmospheric gases. Electrons freed from gas atoms eventually recombine with positive ions to recreate neutral gas atoms, but this takes some time. In the low-pressure environment at the highest altitudes, atoms are spaced far apart and the gases may remain ionized for many hours. At lower altitudes, recombination happens rather quickly, and only constant radiation can keep any appreciable portion of the gas ionized.